Dissertation
Dissertation > Industrial Technology > Light industry,handicrafts > Textile industry,dyeing and finishing industry > General issues > Textile fibers ( textile material )

Study on the Thermal Degradation of Treated Wool (K2MF6 Systems)

Author LiZhi
Tutor TianChunMing
School Hebei University
Course Polymer Chemistry and Physics
Keywords DTA Mechanism Thermal degradation TG Wool Flame retardant
CLC TS102
Type Master's thesis
Year 2003
Downloads 102
Quotes 2
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Paper is divided into three chapters: Chapter : First of the wool flame retardant type , effects and development overview , and then expounded the research status of the flame - retardant wool , and finally explains the purpose, significance and conclusions of the research projects , references References 78 . Chapter II : fluorine potassium titanate and organic acid system , potassium zirconium fluoride and organic acid system , Fluotitanate inorganic salts wool fire-retardant treatment , thermal analysis, infrared spectroscopy , char yield , oxygen index of its fire-retardant properties and thermal degradation behavior was characterized . Comparison of the sample is not flame-retardant , flame-retardant wool has the following changes : ( a ) thermal degradation of the starting temperature is lowered ; oxygen index improver ( b ) ; ( c ) char yield increase ; ( d ) thermal degradation reduces the activation energy . Wool thermal degradation behavior on different systems at the same time to do a preliminary study , wool during pyrolysis , flame retardants wool catalytic decomposition , the decomposition of wool in advance , reducing the burning capacity of the wool , raise the limit oxygen index and char yield . The presence of an organic acid , a stabilizing effect of fluorine of potassium titanate fluorozirconate of Potassium Shared Fluotitanate and inorganic salts have a synergistic effect on the wool flame retardant The Chapter 3 : through a series of analytical methods TBPA and inorganic salts co-processing of flame retardant properties of wool were characterized , and, specifically, the thermal degradation behavior of the flame-retardant wool . Through the comparison processing with the untreated wool , flame-retardant and Thermodynamic Properties , that the flame retardants significantly improve the flame retardancy of wool , and the type of flame retardant mechanism and the influence on the of wool thermal degradation behavior makes a preliminary discussed. The TBPA work in the gas phase , generated in the thermal degradation of wool radical scavenger ( hydrogen bromide ) to prevent flaming combustion , reduce heat weightlessness , and inorganic salts in the solid phase work , catalytic decomposition of wool to improve the char yield .

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