Dissertation
Dissertation > Mathematical sciences and chemical > Chemistry > Organic Chemistry > Aromatic compounds

Synthesis and Properties of Stilbene-Triarylamine as Charge Transfer Materials

Author CaoXiaoDan
Tutor LiuDongZhi
School Tianjin University
Course Applied Chemistry
Keywords Charge transport Electroluminescent Triphenylamine Styrene Crystal structure
CLC O625
Type Master's thesis
Year 2004
Downloads 190
Quotes 3
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The charge transport material is the major component of the charge transport layer in an organic photoconductor , its performance will directly affect the performance of the organic photoconductor . Synthesis excellent performance of the charge transport material is a hot spot of the current research in the field of xerography . Especially in recent years , it electroluminescent and field of flat panel display has broad application prospects greatly broaden the application field of the charge transport material . Look for both charge transport functional materials have excellent electroluminescent properties of organic chemistry and materials science has become a research focus . Therefore , this paper design synthesis two types of styryl phenyl amine charge transport materials , and their structure and performance . Synthetic styryl triphenyl amine charge transport material in the process of improving a synthetic route, to design two synthetic routes . Nitrobenzyl bromide and α- naphthaldehyde as a starting material , by the Wittig reaction , reduction reaction , and the Ullmann reaction synthesis three naphthyl vinyl the triphenylamine compound ; diphenyl bromomethane and nitrobenzaldehyde from the starting material , by the Wittig reaction , reduction reaction , and the Ullmann reaction synthesized three distyryl triphenylamine compound . The resulting nitro intermediates identified by IR , the final product is identified by means of infrared spectroscopy , mass spectrometry and X-ray diffraction analysis . The electrochemical properties of the final product by oxidation reduction potential of the test , wherein the oxidation peak of the two compounds with high sensitivity charge transport material should have an oxidation potential of between 0.50 ~ 0.65V . The photophysical properties of the final product by fluorescence emission spectra for a solution and solids , the results show that they have excellent fluorescence properties in solution and in the solid - state thin-film state , the fluorescence emission wavelength between 467 ~ 492nm , is a blue electroluminescent material . This paper first reported the crystal structures of five compounds .

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